Yes, each small syringe comes with a cap

Can anyone tell me what the exact product/chemicals these syringes are made from?

Plastic, and rubber, I use them to give my dog medicine, It worked very well.

What is the length of the 10ml syringe?

The actual length of the portion that contains the liquid is approximately 2.55'',the overall length of the small syringe is 3.9''

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